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Consider the reversible reaction: 2NO2(g) Consider the reversible reaction: 2NO<sub>2</sub>(g)    N<sub>2</sub>O<sub>4</sub>(g)  If the concentrations of both NO<sub>2</sub> and N<sub>2</sub>O<sub>4</sub> are each 0.016 M, what is the value of Q<sub>c</sub>? A)  0.016 B)  0.50 C)  1.0 D)  2.0 E)  63 N2O4(g) If the concentrations of both NO2 and N2O4 are each 0.016 M, what is the value of Qc?


A) 0.016
B) 0.50
C) 1.0
D) 2.0
E) 63

F) B) and C)
G) C) and D)

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Consider this reaction at equilibrium at a total pressure: 2H2O(g) + O2(g) Consider this reaction at equilibrium at a total pressure: 2H<sub>2</sub>O(g)  + O<sub>2</sub>(g)    2H<sub>2</sub>O<sub>2</sub>(g)  Suppose the volume of this system is twice its initial volume and then equilibrium is reestablished. The new equilibrium total pressure will be A)  more than half the total initial pressure. B)  twice the total pressure. C)  less than half the total initial pressure. D)  unchanged. E)  exactly one half of the initial total pressure. 2H2O2(g) Suppose the volume of this system is twice its initial volume and then equilibrium is reestablished. The new equilibrium total pressure will be


A) more than half the total initial pressure.
B) twice the total pressure.
C) less than half the total initial pressure.
D) unchanged.
E) exactly one half of the initial total pressure.

F) B) and C)
G) B) and D)

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Which substances are included in the equilibrium constant expression, Kc?


A) Only pure solids
B) Only pure liquids
C) Only pure solids and liquids
D) Only gases and dissolved substances
E) All participating substances

F) All of the above
G) C) and D)

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Consider the equilibrium equation C(s) + O2(g) Consider the equilibrium equation C(s) + O<sub>2</sub>(g)   CO<sub>2</sub>(g), where ΔH<sub>rxn</sub> = -393.5 kJ/mol. The reaction will shift toward the ________ if the temperature of the system is decreased. CO2(g), where ΔHrxn = -393.5 kJ/mol. The reaction will shift toward the ________ if the temperature of the system is decreased.

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If, in a particular process, reactants are able to form products, and products are also able to form reactants, then this process may be described as


A) a reversible process.
B) an elementary process.
C) at equilibrium.
D) forbidden.
E) a forward process.

F) C) and D)
G) A) and B)

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At a certain temperature the reaction CO2(g) + H2(g) At a certain temperature the reaction CO<sub>2</sub>(g)  + H<sub>2</sub>(g)    CO(g)  + H<sub>2</sub>O(g)  Has K<sub>c</sub> = 2.50. If 2.00 mol of carbon dioxide and 1.50 mol of hydrogen are placed in a 5.00-L vessel and equilibrium is established, what is the equilibrium concentration of carbon monoxide? A)  0.209 M B)  1.33 M C)  0.267 M D)  0.667 M E)  0.600 M CO(g) + H2O(g) Has Kc = 2.50. If 2.00 mol of carbon dioxide and 1.50 mol of hydrogen are placed in a 5.00-L vessel and equilibrium is established, what is the equilibrium concentration of carbon monoxide?


A) 0.209 M
B) 1.33 M
C) 0.267 M
D) 0.667 M
E) 0.600 M

F) B) and D)
G) B) and C)

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A change in the temperature can change the value of the equilibrium constant.

A) True
B) False

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Hydrogen peroxide (H2O2) decomposes according to the following equation. H2O2(l) → H2O(l) + ½O2(g) . What is KP for this reaction at 25°C? (ΔH° = -98.2 kJ/mol, ΔS° = 70.1 J/K • mol, R = 8.314 J/K • mol)


A) 1.3 × 10-21
B) 20.9
C) 3.46 × 1017
D) 7.4 × 1020
E) 8.6 × 104

F) A) and E)
G) A) and C)

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At 35ºC, the equilibrium constant for the reaction 2NOCl(g) At 35ºC, the equilibrium constant for the reaction 2NOCl(g)    2NO(g)  + Cl<sub>2</sub>(g)  is K<sub>c</sub> = 1.6 × 10<sup>-5</sup>. An equilibrium mixture was found to have the following concentrations of Cl<sub>2</sub> and NOCl: [Cl<sub>2</sub>] = 1.2 × 10<sup>-2 </sup><sup>M</sup>; [NOCl] = 2.8 × 10<sup>-1 </sup><sup>M</sup>. Calculate the concentration of NO(g)  at equilibrium. A)  1.0 × 10<sup>-4 </sup><sup>M</sup> B)  1.0 × 10<sup>-2 </sup><sup>M</sup> C)  2.8 × 10<sup>-1 </sup><sup>M</sup> D)  2.4 × 10<sup>-2 </sup><sup>M</sup> E)  1.6 × 10<sup>-3 </sup><sup>M</sup> 2NO(g) + Cl2(g) is Kc = 1.6 × 10-5. An equilibrium mixture was found to have the following concentrations of Cl2 and NOCl: [Cl2] = 1.2 × 10-2 M; [NOCl] = 2.8 × 10-1 M. Calculate the concentration of NO(g) at equilibrium.


A) 1.0 × 10-4 M
B) 1.0 × 10-2 M
C) 2.8 × 10-1 M
D) 2.4 × 10-2 M
E) 1.6 × 10-3 M

F) None of the above
G) C) and E)

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If Q<K then less reactants are observed as the reaction proceeds to ________.

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The equilibrium constant expression for the reaction CuO(s) + H2(g) The equilibrium constant expression for the reaction CuO(s) + H<sub>2</sub>(g)   Cu(s) + H<sub>2</sub>O(g) is K<sub>c</sub> = [H<sub>2</sub>]/[H<sub>2</sub>O]. Cu(s) + H2O(g) is Kc = [H2]/[H2O].

A) True
B) False

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Which statement is correct?


A) When Q < K then ΔG = 1.
B) When Q < K then ΔG = -ΔS.
C) When Q = K then ΔG = 0.
D) When Q > K then ΔG = 1.
E) When Q > K then ΔG = - RT.

F) B) and E)
G) C) and E)

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Increasing the temperature of an exothermic reaction causes the equilibrium constant to increase and shifts the equilibrium toward products.

A) True
B) False

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For the equilibrium A2(g) For the equilibrium A<sub>2</sub>(g)    2A(g) , if a sample of A<sub>2</sub>(g)  is placed in a sealed container and allowed to come to equilibrium, which graph best represents the relationship between Q<sub>c</sub> and time as equilibrium is established? A)    B)    C)    D)    E)   2A(g) , if a sample of A2(g) is placed in a sealed container and allowed to come to equilibrium, which graph best represents the relationship between Qc and time as equilibrium is established?


A) For the equilibrium A<sub>2</sub>(g)    2A(g) , if a sample of A<sub>2</sub>(g)  is placed in a sealed container and allowed to come to equilibrium, which graph best represents the relationship between Q<sub>c</sub> and time as equilibrium is established? A)    B)    C)    D)    E)
B) For the equilibrium A<sub>2</sub>(g)    2A(g) , if a sample of A<sub>2</sub>(g)  is placed in a sealed container and allowed to come to equilibrium, which graph best represents the relationship between Q<sub>c</sub> and time as equilibrium is established? A)    B)    C)    D)    E)
C) For the equilibrium A<sub>2</sub>(g)    2A(g) , if a sample of A<sub>2</sub>(g)  is placed in a sealed container and allowed to come to equilibrium, which graph best represents the relationship between Q<sub>c</sub> and time as equilibrium is established? A)    B)    C)    D)    E)
D) For the equilibrium A<sub>2</sub>(g)    2A(g) , if a sample of A<sub>2</sub>(g)  is placed in a sealed container and allowed to come to equilibrium, which graph best represents the relationship between Q<sub>c</sub> and time as equilibrium is established? A)    B)    C)    D)    E)
E) For the equilibrium A<sub>2</sub>(g)    2A(g) , if a sample of A<sub>2</sub>(g)  is placed in a sealed container and allowed to come to equilibrium, which graph best represents the relationship between Q<sub>c</sub> and time as equilibrium is established? A)    B)    C)    D)    E)

F) A) and B)
G) A) and C)

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When the following reaction is at equilibrium 2NOCl(g) When the following reaction is at equilibrium 2NOCl(g)   2NO(g) + Cl<sub>2</sub>(g) then [NO]<sup>2</sup> [Cl<sub>2</sub>] = K<sub>c </sub>[NOCl]<sup>2</sup>. 2NO(g) + Cl2(g) then [NO]2 [Cl2] = Kc [NOCl]2.

A) True
B) False

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Suppose 50.0 g of N2O4 is introduced into an evacuated 2.00-L vessel and allowed to come to equilibrium with its decomposition product, N2O4(g) Suppose 50.0 g of N<sub>2</sub>O<sub>4</sub> is introduced into an evacuated 2.00-L vessel and allowed to come to equilibrium with its decomposition product, N<sub>2</sub>O<sub>4</sub>(g)    2NO<sub>2</sub>(g) . For this reaction K<sub>c</sub> = 0.133. Once the system has reached equilibrium, 5.00 g of NO<sub>2</sub> is injected into the vessel, and the system is allowed to equilibrate once again. What is the mass of N<sub>2</sub>O<sub>4</sub> in the final equilibrium mixture? A)  39.5 g B)  35.3 g C)  30.3 g D)  25.2 g E)  43.7 g 2NO2(g) . For this reaction Kc = 0.133. Once the system has reached equilibrium, 5.00 g of NO2 is injected into the vessel, and the system is allowed to equilibrate once again. What is the mass of N2O4 in the final equilibrium mixture?


A) 39.5 g
B) 35.3 g
C) 30.3 g
D) 25.2 g
E) 43.7 g

F) B) and C)
G) A) and B)

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The formation constant for the reaction Ag+(aq) + 2NH3(aq) The formation constant for the reaction Ag<sup>+</sup>(aq)  + 2NH<sub>3</sub>(aq)    Ag(NH<sub>3</sub>) <sub>2</sub><sup>+</sup>(aq)  Is K<sub>f</sub> = 1.7 × 10<sup>7</sup> at 25°C. What is ΔG° at this temperature? (R = 8.314 J/K• mol)  A)  -1.5 kJ/mol B)  -3.5 kJ/mol C)  -18 kJ/mol D)  -23 kJ/mol E)  -41 kJ/mol Ag(NH3) 2+(aq) Is Kf = 1.7 × 107 at 25°C. What is ΔG° at this temperature? (R = 8.314 J/K• mol)


A) -1.5 kJ/mol
B) -3.5 kJ/mol
C) -18 kJ/mol
D) -23 kJ/mol
E) -41 kJ/mol

F) None of the above
G) All of the above

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The observation that at equilibrium, the reaction quotient equals the equilibrium constant, is representative of which law?


A) Law of equal states
B) Reversibility law
C) Law of equivalence
D) Law of reactant-product equivalence
E) Law of mass action

F) A) and B)
G) All of the above

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Consider the chemical reaction 2NH3(g) Consider the chemical reaction 2NH<sub>3</sub>(g)   N<sub>2</sub>(g) + 3H<sub>2</sub>(g). The equilibrium is to be established in a 1.0-L container at 1000 K, where K<sub>c</sub> = 4.0 × 10<sup>-2</sup>. Initially, 1.22 moles of NH<sub>3</sub>(g) are present. What is the equilibrium concentration of H<sub>2</sub>(g)? N2(g) + 3H2(g). The equilibrium is to be established in a 1.0-L container at 1000 K, where Kc = 4.0 × 10-2. Initially, 1.22 moles of NH3(g) are present. What is the equilibrium concentration of H2(g)?

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For the following reaction at equilibrium in a reaction vessel, which one of these changes would cause the I2 concentration to increase? 2NOI(g) For the following reaction at equilibrium in a reaction vessel, which one of these changes would cause the I<sub>2</sub> concentration to increase? 2NOI(g)    2NO(g)  + I<sub>2</sub>(g) , ΔHº<sub>rxn </sub>= 45.3 kJ/mol A)  Add some NO B)  Expand the gas mixture into a larger volume C)  Decrease the temperature D)  Increase the system pressure E)  Remove some NOI 2NO(g) + I2(g) , ΔHºrxn = 45.3 kJ/mol


A) Add some NO
B) Expand the gas mixture into a larger volume
C) Decrease the temperature
D) Increase the system pressure
E) Remove some NOI

F) A) and E)
G) C) and E)

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